| 23-Dec-95 EPL 1995/1996 - M.19 | | Liverpool | - | Arsenal | | |
| 01-May-96 EPL 1995/1996 - M.30 | | Arsenal | - | Liverpool | | |
| 19-Aug-96 EPL 1996/1997 - M.2 | | Liverpool | 2-0 | Arsenal | | Willard |
| 24-Mar-97 EPL 1996/1997 - M.30 | | Arsenal | 1-2 | Liverpool | | Ashby |
| 30-Nov-97 EPL 1997/1998 - M.16 | | Arsenal | 0-1 | Liverpool | | Poll |
| 06-May-98 EPL 1997/1998 - M.32 | | Liverpool | 4-0 | Arsenal | | Wilkie |
| 22-Aug-98 EPL 1998/1999 - M.2 | | Liverpool | 0-0 | Arsenal | | Elleray |
| 28-Aug-99 EPL 1999/2000 - M.6 | | Liverpool | 2-0 | Arsenal | | Gallagher |
| 13-Feb-00 EPL 1999/2000 - M.25 | | Arsenal | 0-1 | Liverpool | | Dunn |
| 21-Aug-00 EPL 2000/2001 - M.2 | | Arsenal | 2-0 | Liverpool | | Poll |
| 23-Dec-00 EPL 2000/2001 - M.19 | | Liverpool | 4-0 | Arsenal | | Durkin |
| 23-Dec-01 EPL 2001/2002 - M.18 | | Liverpool | 1-2 | Arsenal | | Durkin |
| 13-Jan-02 EPL 2001/2002 - M.22 | | Arsenal | 1-1 | Liverpool | | Dunn |
| 29-Dec-02 EPL 2002/2003 - M.21 | | Arsenal | 1-1 | Liverpool | | Winter, J |
| 29-Jan-03 EPL 2002/2003 - M.25 | | Liverpool | 2-2 | Arsenal | | Halsey |
| 04-Oct-03 EPL 2003/2004 - M.8 | | Liverpool | 1-2 | Arsenal | | Barber |
| 09-Apr-04 EPL 2003/2004 - M.32 | | Arsenal | 4-2 | Liverpool | | Wiley |
| 28-Nov-04 EPL 2004/2005 - M.15 | | Liverpool | 2-1 | Arsenal | | Wiley |
| 08-May-05 EPL 2004/2005 - M.37 | | Arsenal | 3-1 | Liverpool | | Poll |
| 14-Feb-06 EPL 2005/2006 - M.4 | | Liverpool | 1-0 | Arsenal | | Poll |
| 12-Mar-06 EPL 2005/2006 - M.29 | | Arsenal | 2-1 | Liverpool | | Bennett |
| 12-Nov-06 EPL 2006/2007 - M.12 | | Arsenal | 3-0 | Liverpool | | Clattenburg |
| 06-Jan-07 FA Cup 2006/2007 - M.3 | Rounds | Liverpool | 1-3 | Arsenal | | Bennett |
| 31-Mar-07 EPL 2006/2007 - M.31 | | Liverpool | 4-1 | Arsenal | | Bennett |
| 28-Oct-07 EPL 2007/2008 - M.11 | | Liverpool | 1-1 | Arsenal | | Webb, H |
| 02-Apr-08 Champions 2007/2008 - M.9 | Quarterfinals | Arsenal | 1-1 | Liverpool | |  Vink |
| 05-Apr-08 EPL 2007/2008 - M.33 | | Arsenal | 1-1 | Liverpool | | Dowd |
| 08-Apr-08 Champions 2007/2008 - M.10 | Quarterfinals | Liverpool | 4-2 | Arsenal | |  Fröjdfeldt |
| 21-Dec-08 EPL 2008/2009 - M.18 | | Arsenal | 1-1 | Liverpool | | Webb, H |
| 21-Apr-09 EPL 2008/2009 - M.33 | | Liverpool | 4-4 | Arsenal | | Webb, H |
| 28-Oct-09 League Cup 2009/2010 - M.4 | Fourth Round | Arsenal | 2-1 | Liverpool | | Wiley |
| 13-Dec-09 EPL 2009/2010 - M.16 | | Liverpool | 1-2 | Arsenal | | Webb, H |
| 10-Feb-10 EPL 2009/2010 - M.26 | | Arsenal | 1-0 | Liverpool | | Webb, H |
| 15-Aug-10 EPL 2010/2011 - M.1 | | Liverpool | 1-1 | Arsenal | | Atkinson, M |
| 17-Apr-11 EPL 2010/2011 - M.33 | | Arsenal | 1-1 | Liverpool | | Marriner |
| 20-Aug-11 EPL 2011/2012 - M.2 | | Arsenal | 0-2 | Liverpool | | Atkinson, M |
| 03-Mar-12 EPL 2011/2012 - M.27 | | Liverpool | 1-2 | Arsenal | | Halsey |
| 02-Sep-12 EPL 2012/2013 - M.3 | | Liverpool | 0-2 | Arsenal | | Webb, H |
| 30-Jan-13 EPL 2012/2013 - M.24 | | Arsenal | 2-2 | Liverpool | | Friend |
| 02-Nov-13 EPL 2013/2014 - M.10 | | Arsenal | 2-0 | Liverpool | | |
| 08-Feb-14 EPL 2013/2014 - M.25 | | Liverpool | 5-1 | Arsenal | | Oliver, M |
| 16-Feb-14 FA Cup 2013/2014 - M.8 | Fifth Round | Arsenal | 2-1 | Liverpool | | Webb, H |
| 21-Dec-14 EPL 2014/2015 - M.17 | | Liverpool | 2-2 | Arsenal | | Oliver, M |
| 04-Apr-15 EPL 2014/2015 - M.31 | | Arsenal | 4-1 | Liverpool | | Taylor, A |
| 24-Aug-15 EPL 2015/2016 - M.3 | | Arsenal | 0-0 | Liverpool | | Oliver, M |
| 13-Jan-16 EPL 2015/2016 - M.21 | | Liverpool | 3-3 | Arsenal | | Jones, M |
| 14-Aug-16 EPL 2016/2017 - M.1 | | Arsenal | 3-4 | Liverpool | | Oliver, M |
| 26-Aug-16 PL2 2016/2017 - M.3 | | Arsenal | 1-3 | Liverpool | | Treleaven |
| 12-Dec-16 PL2 2016/2017 - M.12 | | Liverpool | 3-2 | Arsenal | | Rushton |
| 04-Mar-17 EPL 2016/2017 - M.27 | | Liverpool | 3-1 | Arsenal | | Madley, R |
| 25-Aug-17 PL2 2017/2018 - M.3 | | Arsenal | 1-2 | Liverpool | | Brook |
| 27-Aug-17 EPL 2017/2018 - M.3 | | Liverpool | 4-0 | Arsenal | | Atkinson, M |
| 22-Dec-17 EPL 2017/2018 - M.19 | | Arsenal | 3-3 | Liverpool | | Atkinson, M |
| 06-Apr-18 PL2 2017/2018 - M.14 | | Liverpool | 1-1 | Arsenal | | Lucas |
| 21-Sep-18 PL2 2018/2019 - M.6 | | Arsenal | 4-0 | Liverpool | | Wood |
| 03-Nov-18 EPL 2018/2019 - M.11 | | Arsenal | 1-1 | Liverpool | | Marriner |
| 08-Dec-18 PL2 2018/2019 - M.12 | | Liverpool | 4-1 | Arsenal | | Middleton |
| 29-Dec-18 EPL 2018/2019 - M.20 | | Liverpool | 5-1 | Arsenal | | Oliver, M |
| 24-Aug-19 EPL 2019/2020 - M.3 | | Liverpool | 3-1 | Arsenal | | Taylor, A |
| 28-Sep-19 PL2 2019/2020 - M.7 | | Arsenal U21 | 2-2 | Liverpool U21 | | Yianni |
| 30-Oct-19 League Cup 2019/2020 - M.4 | Fourth Round | Liverpool | 5-5
(5-4) | Arsenal | | Marriner |
| 01-Feb-20 PL2 2019/2020 - M.16 | | Liverpool U21 | 3-0 | Arsenal U21 | | Woods |
| 15-Jul-20 EPL 2019/2020 - M.36 | | Arsenal | 2-1 | Liverpool | | Tierney |
| 29-Aug-20 Comty. Shield 2020 - M.1 | Final | Arsenal | 1-1
(5-4) | Liverpool | | Marriner |
| 28-Sep-20 EPL 2020/2021 - M.3 | | Liverpool | 3-1 | Arsenal | | Pawson |
| 01-Oct-20 League Cup 2020/2021 - M.4 | Fourth Round | Liverpool | 0-0
(4-5) | Arsenal | | Friend |
| 30-Oct-20 PL2 2020/2021 - M.7 | | Arsenal U21 | 0-1 | Liverpool U21 | | Durkin, J |
| 27-Feb-21 PL2 2020/2021 - M.20 | | Liverpool U21 | 4-0 | Arsenal U21 | | Welch |
| 03-Apr-21 EPL 2020/2021 - M.30 | | Arsenal | 0-3 | Liverpool | | Attwell |
| 16-Oct-21 PL2 2021/2022 - M.8 | | Liverpool U21 | 3-0 | Arsenal U21 | | Middleton |
| 20-Nov-21 EPL 2021/2022 - M.12 | | Liverpool | 4-0 | Arsenal | | Oliver, M |
| 13-Jan-22 League Cup 2021/2022 - M.6 | Semi-finals | Liverpool | 0-0 | Arsenal | | Oliver, M |
| 20-Jan-22 League Cup 2021/2022 - M.7 | Semi-finals | Arsenal | 0-2 | Liverpool | | Atkinson, M |
| 25-Feb-22 PL2 2021/2022 - M.21 | | Arsenal U21 | 1-4 | Liverpool U21 | | Bishop |
| 16-Mar-22 EPL 2021/2022 - M.27 | | Arsenal | 0-2 | Liverpool | | Marriner |
| 01-Oct-22 PL2 2022/2023 - M.8 | | Liverpool U21 | 1-1 | Arsenal U21 | | Richardson, D |
| 09-Oct-22 EPL 2022/2023 - M.10 | | Arsenal | 3-2 | Liverpool | | Oliver, M |
| 06-Mar-23 PL2 2022/2023 - M.21 | | Arsenal U21 | 0-1 | Liverpool U21 | | Miles |
| 09-Apr-23 EPL 2022/2023 - M.30 | | Liverpool | 2-2 | Arsenal | | Tierney |
| 23-Dec-23 EPL 2023/2024 - M.18 | | Liverpool | 1-1 | Arsenal | | Kavanagh |
| 07-Jan-24 FA Cup 2023/2024 - M.7 | Third Round | Arsenal | 0-2 | Liverpool | | Brooks |
| 04-Feb-24 EPL 2023/2024 - M.23 | | Arsenal | 3-1 | Liverpool | | Taylor, A |
| 28-Apr-24 PL2 2023/2024 - M.20 | League | Liverpool U21 | 0-2 | Arsenal U21 | | Wyatt |
| 27-Oct-24 EPL 2024/2025 - M.9 | | Arsenal | 2-2 | Liverpool | | Taylor, A |
| 10-May-25 EPL 2024/2025 - M.36 | | Liverpool | - | Arsenal | | |
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