| 31-Dec-95 EPL 1995/1996 - M.20 | | A.Villa | - | Liverpool | | |
| 02-Mar-96 EPL 1995/1996 - M.29 | | Liverpool | - | A.Villa | | |
| 18-Jan-97 EPL 1996/1997 - M.24 | | Liverpool | 3-0 | A.Villa | | Dilkes |
| 02-Mar-97 EPL 1996/1997 - M.28 | | A.Villa | 1-0 | Liverpool | | Dunn |
| 22-Sep-97 EPL 1997/1998 - M.8 | | Liverpool | 3-0 | A.Villa | | Bodenham |
| 28-Feb-98 EPL 1997/1998 - M.28 | | A.Villa | 2-1 | Liverpool | | Poll |
| 21-Nov-98 EPL 1998/1999 - M.14 | | A.Villa | 2-4 | Liverpool | | Jones, P |
| 17-Apr-99 EPL 1998/1999 - M.34 | | Liverpool | 0-1 | A.Villa | | Winter, J |
| 02-Oct-99 EPL 1999/2000 - M.10 | | A.Villa | 0-0 | Liverpool | | Harris |
| 15-Mar-00 EPL 1999/2000 - M.35 | | Liverpool | 0-0 | A.Villa | | Bennett |
| 06-Sep-00 EPL 2000/2001 - M.4 | | Liverpool | 3-1 | A.Villa | | Barry |
| 13-Jan-01 EPL 2000/2001 - M.23 | | A.Villa | 0-3 | Liverpool | | Barber |
| 08-Sep-01 EPL 2001/2002 - M.4 | | Liverpool | 1-3 | A.Villa | | D'Urso |
| 26-Dec-01 EPL 2001/2002 - M.19 | | A.Villa | 1-2 | Liverpool | | D'Urso |
| 18-Aug-02 EPL 2002/2003 - M.1 | | A.Villa | 0-1 | Liverpool | | D'Urso |
| 11-Jan-03 EPL 2002/2003 - M.23 | | Liverpool | 1-1 | A.Villa | | Durkin |
| 24-Aug-03 EPL 2003/2004 - M.2 | | A.Villa | 0-0 | Liverpool | | Durkin |
| 10-Jan-04 EPL 2003/2004 - M.21 | | Liverpool | 1-0 | A.Villa | | Barber |
| 15-May-05 EPL 2004/2005 - M.38 | | Liverpool | 2-1 | A.Villa | | Knight |
| 05-Nov-05 EPL 2005/2006 - M.12 | | A.Villa | 0-2 | Liverpool | | Bennett |
| 29-Apr-06 EPL 2005/2006 - M.37 | | Liverpool | 3-1 | A.Villa | | Halsey |
| 28-Oct-06 EPL 2006/2007 - M.10 | | Liverpool | 3-1 | A.Villa | | Bennett |
| 18-Mar-07 EPL 2006/2007 - M.30 | | A.Villa | 0-0 | Liverpool | | Mason |
| 11-Aug-07 EPL 2007/2008 - M.1 | | A.Villa | 1-2 | Liverpool | | Riley |
| 21-Jan-08 EPL 2007/2008 - M.23 | | Liverpool | 2-2 | A.Villa | | Clattenburg |
| 31-Aug-08 EPL 2008/2009 - M.3 | | A.Villa | 0-0 | Liverpool | | Atkinson, M |
| 22-Mar-09 EPL 2008/2009 - M.30 | | Liverpool | 5-0 | A.Villa | | Atkinson, M |
| 24-Aug-09 EPL 2009/2010 - M.3 | | Liverpool | 1-3 | A.Villa | | Atkinson, M |
| 29-Dec-09 EPL 2009/2010 - M.20 | | A.Villa | 0-1 | Liverpool | | Probert |
| 06-Dec-10 EPL 2010/2011 - M.16 | | Liverpool | 3-0 | A.Villa | | Dowd |
| 22-May-11 EPL 2010/2011 - M.38 | | A.Villa | 1-0 | Liverpool | | Probert |
| 18-Dec-11 EPL 2011/2012 - M.16 | | A.Villa | 0-2 | Liverpool | | Walton |
| 02-Apr-12 EPL Reserves 2011/2012 - M.21 | League | A.Villa | 1-4 | Liverpool | | Plane |
| 07-Apr-12 EPL 2011/2012 - M.32 | | Liverpool | 1-1 | A.Villa | | Oliver, M |
| 15-Dec-12 EPL 2012/2013 - M.17 | | Liverpool | 1-3 | A.Villa | | Swarbrick |
| 31-Mar-13 EPL 2012/2013 - M.31 | | A.Villa | 1-2 | Liverpool | | Mason |
| 24-Aug-13 EPL 2013/2014 - M.2 | | A.Villa | 0-1 | Liverpool | | Clattenburg |
| 18-Jan-14 EPL 2013/2014 - M.22 | | Liverpool | 2-2 | A.Villa | | Moss |
| 13-Sep-14 EPL 2014/2015 - M.4 | | Liverpool | 0-1 | A.Villa | | Mason |
| 17-Jan-15 EPL 2014/2015 - M.22 | | A.Villa | 0-2 | Liverpool | | Clattenburg |
| 19-Apr-15 FA Cup 2014/2015 - M.12 | Semi-finals | A.Villa | 2-1 | Liverpool | | Oliver, M |
| 26-Sep-15 EPL 2015/2016 - M.7 | | Liverpool | 3-2 | A.Villa | | Moss |
| 14-Feb-16 EPL 2015/2016 - M.26 | | A.Villa | 0-6 | Liverpool | | Swarbrick |
| 02-Nov-19 EPL 2019/2020 - M.11 | | A.Villa | 1-2 | Liverpool | | Moss |
| 17-Dec-19 League Cup 2019/2020 - M.5 | Fifth Round | A.Villa | 5-0 | Liverpool | | Mason |
| 05-Jul-20 EPL 2019/2020 - M.33 | | Liverpool | 2-0 | A.Villa | | Tierney |
| 04-Oct-20 EPL 2020/2021 - M.4 | | A.Villa | 7-2 | Liverpool | | Atkinson, M |
| 08-Jan-21 FA Cup 2020/2021 - M.3 | Third Round | A.Villa | 1-4 | Liverpool | | Pawson |
| 10-Apr-21 EPL 2020/2021 - M.31 | | Liverpool | 2-1 | A.Villa | | Tierney |
| 11-Dec-21 EPL 2021/2022 - M.16 | | Liverpool | 1-0 | A.Villa | | Attwell |
| 10-May-22 EPL 2021/2022 - M.33 | | A.Villa | 1-2 | Liverpool | | Moss |
| 26-Dec-22 EPL 2022/2023 - M.17 | | A.Villa | 1-3 | Liverpool | | Tierney |
| 20-May-23 EPL 2022/2023 - M.37 | | Liverpool | 1-1 | A.Villa | | Brooks |
| 03-Sep-23 EPL 2023/2024 - M.4 | | Liverpool | 3-0 | A.Villa | | Hooper |
| 03-Mar-24 PL2 2023/2024 - M.15 | League | Liverpool U21 | 0-2 | A.Villa U21 | | Marsden |
| 13-May-24 EPL 2023/2024 - M.37 | | A.Villa | 3-3 | Liverpool | | Hooper |
| 09-Nov-24 EPL 2024/2025 - M.11 | | Liverpool | 2-0 | A.Villa | | Coote |
| 19-Feb-25 EPL 2024/2025 - M.29 | | A.Villa | 2-2 | Liverpool | | Attwell |
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