| 30-Sep-07 SPL 2007/2008 - M.8 | | St Mirren | 1-3 | Hearts | | Underhill |
| 26-Dec-07 SPL 2007/2008 - M.19 | | Hearts | 0-1 | St Mirren | | |
| 15-Mar-08 SPL 2007/2008 - M.30 | | St Mirren | 1-1 | Hearts | | Collum |
| 19-Apr-08 SPL 2007/2008 - M.34 | | Hearts | 3-2 | St Mirren | | McCurry |
| 23-Aug-08 SPL 2008/2009 - M.3 | | Hearts | 2-1 | St Mirren | | Murray |
| 21-Feb-09 SPL 2008/2009 - M.26 | | Hearts | 1-1 | St Mirren | | Somers |
| 03-Oct-09 SPL 2009/2010 - M.7 | | St Mirren | 2-1 | Hearts | | Winter, B |
| 16-Jan-10 SPL 2009/2010 - M.20 | | Hearts | 1-0 | St Mirren | | Reilly |
| 03-Apr-10 SPL 2009/2010 - M.32 | | St Mirren | 1-1 | Hearts | | Brines |
| 23-Oct-10 SPL 2010/2011 - M.9 | | Hearts | 3-0 | St Mirren | | Murray |
| 29-Dec-10 SPL 2010/2011 - M.19 | | St Mirren | 0-2 | Hearts | | Allan |
| 19-Mar-11 SPL 2010/2011 - M.30 | | Hearts | 3-2 | St Mirren | | Finnie |
| 17-Sep-11 SPL 2011/2012 - M.8 | | Hearts | 2-0 | St Mirren | | Richmond |
| 05-Nov-11 SPL 2011/2012 - M.14 | | St Mirren | 0-0 | Hearts | | Conroy |
| 14-Jan-12 SPL 2011/2012 - M.23 | | Hearts | 5-2 | St Mirren | | McLean |
| 10-Mar-12 Scottish Cup 2011/2012 - M.11 | Quarter Final | Hearts | 2-2 | St Mirren | | Reilly |
| 21-Mar-12 Scottish Cup 2011/2012 - M.12 | Quarter Final | St Mirren | 0-2 | Hearts | | Reilly |
| 15-Sep-12 SPL 2012/2013 - M.6 | | St Mirren | 2-0 | Hearts | | Murray |
| 17-Nov-12 SPL 2012/2013 - M.14 | | Hearts | 1-0 | St Mirren | | Madden |
| 27-Feb-13 SPL 2012/2013 - M.29 | | St Mirren | 2-0 | Hearts | | |
| 04-May-13 SPL 2012/2013 - M.36 | | Hearts | 3-0 | St Mirren | | |
| 05-Oct-13 SPFL 2013/2014 - M.9 | | Hearts | 0-2 | St Mirren | | Thomson |
| 29-Dec-13 SPFL 2013/2014 - M.19 | | St Mirren | 1-1 | Hearts | | Clancy |
| 29-Jan-14 SPFL 2013/2014 - M.25 | | Hearts | 2-1 | St Mirren | | McLean |
| 10-May-14 SPFL 2013/2014 - M.38 | | St Mirren | 1-1 | Hearts | | Finnie |
| 01-Sep-18 SPFL 2018/2019 - M.4 | | Hearts | 4-1 | St Mirren | | Clancy |
| 24-Nov-18 SPFL 2018/2019 - M.14 | | St Mirren | 2-0 | Hearts | | Thomson |
| 23-Feb-19 SPFL 2018/2019 - M.27 | | Hearts | 1-1 | St Mirren | | Robertson |
| 28-Sep-19 SPFL 2019/2020 - M.7 | | St Mirren | 0-0 | Hearts | | Dallas, A |
| 09-Nov-19 SPFL 2019/2020 - M.13 | | Hearts | 5-2 | St Mirren | | Anderson |
| 11-Mar-20 SPFL 2019/2020 - M.28 | | St Mirren | 1-0 | Hearts | | Muir |
| 07-Aug-21 SPFL 2021/2022 - M.2 | League | St Mirren | 1-2 | Hearts | | Duncan, G |
| 27-Nov-21 SPFL 2021/2022 - M.15 | League | Hearts | 2-0 | St Mirren | | Muir |
| 26-Feb-22 SPFL 2021/2022 - M.28 | League | St Mirren | 0-2 | Hearts | | Aitken |
| 12-Mar-22 Scottish Cup 2021/2022 - M.4 | Quarter-finals | Hearts | 4-2 | St Mirren | | Madden |
| 07-Jan-23 SPFL 2022/2023 - M.21 | League | St Mirren | 1-1 | Hearts | | Graham, C |
| 13-Jan-23 SPFL 2022/2023 - M.7 | League | Hearts | 1-0 | St Mirren | | Munro, David |
| 08-Apr-23 SPFL 2022/2023 - M.31 | League | Hearts | 0-2 | St Mirren | | McDermid, M |
| 13-May-23 SPFL 2022/2023 - M.35 | Championship | St Mirren | 2-2 | Hearts | | Dickinson |
| 23-Sep-23 SPFL 2023/2024 - M.6 | League | St Mirren | 1-0 | Hearts | | Walsh |
| 23-Dec-23 SPFL 2023/2024 - M.19 | League | Hearts | 2-0 | St Mirren | | Walsh |
| 06-Apr-24 SPFL 2023/2024 - M.32 | League | St Mirren | 1-2 | Hearts | | Muir |
| 15-May-24 SPFL 2023/2024 - M.37 | Championship | St Mirren | 2-2 | Hearts | | Beaton, J |
| 21-Sep-24 SPFL 2024/2025 - M.15 | League | St Mirren | 2-1 | Hearts | | Robertson |
| 19-Oct-24 SPFL 2024/2025 - M.8 | League | Hearts | 4-0 | St Mirren | | Steven |
| 10-Feb-25 Scottish Cup 2024/2025 - M.5 | 1/8 Finals | St Mirren | 1-1
(2-4) | Hearts | | Robertson |
| 26-Feb-25 SPFL 2024/2025 - M.28 | League | Hearts | 3-1 | St Mirren | | Anderson |
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