| 12-Nov-06 Eredivisie 2006/2007 - M.12 | | Ajax | 0-1 | PSV | | Wegereef |
| 18-Mar-07 Eredivisie 2006/2007 - M.29 | | PSV | 1-5 | Ajax | | Braamhaar |
| 30-Jan-08 Eredivisie 2007/2008 - M.15 | | Ajax | 0-2 | PSV | | Wegereef |
| 19-Mar-08 Eredivisie 2007/2008 - M.28 | | PSV | 0-0 | Ajax | | Braamhaar |
| 16-Nov-08 Eredivisie 2008/2009 - M.11 | | Ajax | 4-1 | PSV | | Blom |
| 19-Apr-09 Eredivisie 2008/2009 - M.31 | | PSV | 6-2 | Ajax | | Wegereef |
| 16-Aug-09 Eredivisie 2009/2010 - M.3 | | PSV | 4-3 | Ajax | | Vink |
| 14-Mar-10 Eredivisie 2009/2010 - M.27 | | Ajax | 4-1 | PSV | | Blom |
| 20-Nov-10 Eredivisie 2010/2011 - M.15 | | Ajax | 0-0 | PSV | | Kuipers |
| 27-Feb-11 Eredivisie 2010/2011 - M.25 | | PSV | 0-0 | Ajax | | Braamhaar |
| 18-Sep-11 Eredivisie 2011/2012 - M.6 | | PSV | 2-2 | Ajax | | Kuipers |
| 25-Mar-12 Eredivisie 2011/2012 - M.27 | | Ajax | 2-0 | PSV | | Vink |
| 05-Aug-12 Dutch Supercup 2012 - M.1 | Final | PSV | 4-2 | Ajax | | Kuipers |
| 01-Dec-12 Eredivisie 2012/2013 - M.15 | | Ajax | 3-1 | PSV | | Kuipers |
| 14-Apr-13 Eredivisie 2012/2013 - M.30 | | PSV | 2-3 | Ajax | | Kuipers |
| 22-Sep-13 Eredivisie 2013/2014 - M.7 | | PSV | 4-0 | Ajax | | |
| 19-Jan-14 Eredivisie 2013/2014 - M.19 | | Ajax | 1-0 | PSV | | Kuipers |
| 24-Aug-14 Eredivisie 2014/2015 - M.3 | | Ajax | 1-3 | PSV | | Kuipers |
| 01-Mar-15 Eredivisie 2014/2015 - M.25 | | PSV | 1-3 | Ajax | | Makkelie |
| 04-Oct-15 Eredivisie 2015/2016 - M.8 | | Ajax | 1-2 | PSV | | Nijhuis |
| 20-Mar-16 Eredivisie 2015/2016 - M.28 | | PSV | 0-2 | Ajax | | Kuipers |
| 18-Dec-16 Eredivisie 2016/2017 - M.17 | | Ajax | 1-1 | PSV | | van Boekel |
| 23-Apr-17 Eredivisie 2016/2017 - M.32 | | PSV | 1-0 | Ajax | | Blom |
| 10-Dec-17 Eredivisie 2017/2018 - M.15 | | Ajax | 3-0 | PSV | | Blom |
| 15-Apr-18 Eredivisie 2017/2018 - M.31 | | PSV | 3-0 | Ajax | | Makkelie |
| 23-Sep-18 Eredivisie 2018/2019 - M.6 | | PSV | 3-0 | Ajax | | Makkelie |
| 31-Mar-19 Eredivisie 2018/2019 - M.27 | | Ajax | 3-1 | PSV | | Kuipers |
| 27-Jul-19 Dutch Supercup 2019 - M.1 | Final | Ajax | 2-0 | PSV | | Higler |
| 22-Sep-19 Eredivisie 2019/2020 - M.7 | | PSV | 1-1 | Ajax | | Makkelie |
| 02-Feb-20 Eredivisie 2019/2020 - M.21 | | Ajax | 1-0 | PSV | | Kuipers |
| 10-Jan-21 Eredivisie 2020/2021 - M.15 | | Ajax | 2-2 | PSV | | Kuipers |
| 28-Feb-21 Eredivisie 2020/2021 - M.24 | | PSV | 1-1 | Ajax | | Makkelie |
| 07-Aug-21 Dutch Supercup 2021 - | Final | Ajax | 0-4 | PSV | | Kuipers |
| 24-Oct-21 Eredivisie 2021/2022 - M.10 | | Ajax | 5-0 | PSV | | Gözübüyük |
| 23-Jan-22 Eredivisie 2021/2022 - M.20 | | PSV | 1-2 | Ajax | | Makkelie |
| 17-Apr-22 KNVB Beker 2021/2022 - M.7 | Final | PSV | - | Ajax | | |
| 30-Jul-22 Dutch Supercup 2022 - | Final | Ajax | 3-5 | PSV | | Higler |
| 06-Nov-22 Eredivisie 2022/2023 - M.13 | | Ajax | 1-2 | PSV | | Makkelie |
| 23-Apr-23 Eredivisie 2022/2023 - M.30 | | PSV | 3-0 | Ajax | | Gözübüyük |
| 30-Apr-23 KNVB Beker 2022/2023 - M.8 | Final | Ajax | 1-1
(2-3) | PSV | | Higler |
| 29-Oct-23 Eredivisie 2023/2024 - M.10 | | PSV | 5-2 | Ajax | | Makkelie |
| 03-Feb-24 Eredivisie 2023/2024 - M.20 | | Ajax | 1-1 | PSV | | Gözübüyük |
| 02-Nov-24 Eredivisie 2024/2025 - M.11 | | Ajax | 3-2 | PSV | | Gözübüyük |
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