| 03-Sep-07 SPL 2007/2008 - M.5 | | Mothrwell | 0-2 | Hearts | | Richmond |
| 08-Dec-07 SPL 2007/2008 - M.16 | | Hearts | 1-2 | Mothrwell | | |
| 23-Feb-08 SPL 2007/2008 - M.27 | | Mothrwell | 0-1 | Hearts | | Thomson |
| 09-Aug-08 SPL 2008/2009 - M.1 | | Hearts | 3-2 | Mothrwell | | Brines |
| 07-Jan-09 SPL 2008/2009 - M.17 | | Mothrwell | 1-0 | Hearts | | Somers |
| 04-Mar-09 SPL 2008/2009 - M.28 | | Hearts | 2-1 | Mothrwell | | Winter, B |
| 31-Oct-09 SPL 2009/2010 - M.10 | | Mothrwell | 1-0 | Hearts | | Somers |
| 30-Dec-09 SPL 2009/2010 - M.18 | | Hearts | 1-0 | Mothrwell | | Allan |
| 13-Mar-10 SPL 2009/2010 - M.30 | | Mothrwell | 3-1 | Hearts | | Finnie |
| 24-Apr-10 SPL 2009/2010 - M.35 | | Hearts | 0-2 | Mothrwell | | Winter, B |
| 25-Sep-10 SPL 2010/2011 - M.6 | | Hearts | 0-2 | Mothrwell | | Tumilty |
| 14-Dec-10 SPL 2010/2011 - M.15 | | Mothrwell | 1-2 | Hearts | | Reilly |
| 09-Apr-11 SPL 2010/2011 - M.32 | | Hearts | 0-0 | Mothrwell | | Thomson |
| 23-Apr-11 SPL 2010/2011 - M.34 | | Hearts | 3-3 | Mothrwell | | Collum |
| 07-Aug-11 SPL 2011/2012 - M.3 | | Mothrwell | 1-0 | Hearts | | Reilly |
| 24-Dec-11 SPL 2011/2012 - M.20 | | Hearts | 2-0 | Mothrwell | | Allan |
| 18-Feb-12 SPL 2011/2012 - M.27 | | Mothrwell | 3-0 | Hearts | | Muir |
| 01-May-12 SPL 2011/2012 - M.36 | | Hearts | 0-1 | Mothrwell | | Winter, B |
| 20-Oct-12 SPL 2012/2013 - M.10 | | Hearts | 1-0 | Mothrwell | | Collum |
| 24-Nov-12 SPL 2012/2013 - M.15 | | Mothrwell | 0-0 | Hearts | | Allan |
| 02-Mar-13 SPL 2012/2013 - M.24 | | Hearts | 1-2 | Mothrwell | | |
| 19-Oct-13 SPFL 2013/2014 - M.10 | | Mothrwell | 2-1 | Hearts | | Colvin |
| 11-Jan-14 SPFL 2013/2014 - M.22 | | Hearts | 0-1 | Mothrwell | | Collum |
| 01-Mar-14 SPFL 2013/2014 - M.28 | | Mothrwell | 4-1 | Hearts | | Beaton, J |
| 12-Aug-15 SPFL 2015/2016 - M.3 | | Hearts | 2-0 | Mothrwell | | Colvin |
| 28-Nov-15 SPFL 2015/2016 - M.16 | | Mothrwell | 2-2 | Hearts | | McLean |
| 16-Jan-16 SPFL 2015/2016 - M.23 | | Hearts | 6-0 | Mothrwell | | Clancy |
| 23-Apr-16 SPFL 2015/2016 - M.34 | | Mothrwell | 1-0 | Hearts | | Dallas, A |
| 30-Sep-16 SPFL 2016/2017 - M.8 | | Mothrwell | 1-3 | Hearts | | McLean |
| 26-Nov-16 SPFL 2016/2017 - M.15 | | Hearts | 3-0 | Mothrwell | | Madden |
| 04-Feb-17 SPFL 2016/2017 - M.24 | | Mothrwell | 0-3 | Hearts | | Dallas, A |
| 26-Aug-17 SPFL 2017/2018 - M.4 | | Mothrwell | 2-1 | Hearts | | Beaton, J |
| 09-Dec-17 SPFL 2017/2018 - M.17 | | Hearts | 1-0 | Mothrwell | | Dallas, A |
| 27-Jan-18 SPFL 2017/2018 - M.24 | | Hearts | 1-1 | Mothrwell | | Collum |
| 15-Sep-18 SPFL 2018/2019 - M.5 | | Mothrwell | 0-1 | Hearts | | Madden |
| 08-Dec-18 SPFL 2018/2019 - M.17 | | Hearts | 1-0 | Mothrwell | | Collum |
| 17-Feb-19 SPFL 2018/2019 - M.26 | | Mothrwell | 2-1 | Hearts | | Walsh |
| 14-Sep-19 SPFL 2019/2020 - M.5 | | Hearts | 2-3 | Mothrwell | | Anderson |
| 07-Dec-19 SPFL 2019/2020 - M.17 | | Mothrwell | 1-0 | Hearts | | Muir |
| 07-Mar-20 SPFL 2019/2020 - M.30 | | Hearts | 1-1 | Mothrwell | | Robertson |
| 02-Oct-21 SPFL 2021/2022 - M.8 | League | Hearts | 2-0 | Mothrwell | | Munro, David |
| 20-Nov-21 SPFL 2021/2022 - M.14 | League | Mothrwell | 2-0 | Hearts | | Collum |
| 29-Jan-22 SPFL 2021/2022 - M.24 | League | Hearts | 2-0 | Mothrwell | | Napier |
| 11-May-22 SPFL 2021/2022 - M.38 | Championship | Mothrwell | 2-1 | Hearts | | McDermid, M |
| 18-Sep-22 SPFL 2022/2023 - M.8 | League | Mothrwell | 0-3 | Hearts | | Walsh |
| 06-Nov-22 SPFL 2022/2023 - M.14 | League | Hearts | 3-2 | Mothrwell | | Clancy |
| 19-Feb-23 SPFL 2022/2023 - M.26 | League | Mothrwell | 2-0 | Hearts | | Robertson |
| 03-Sep-23 SPFL 2023/2024 - M.4 | League | Hearts | 0-1 | Mothrwell | | Irvine, G |
| 11-Nov-23 SPFL 2023/2024 - M.13 | League | Mothrwell | 1-2 | Hearts | | Munro, David |
| 17-Feb-24 SPFL 2023/2024 - M.26 | League | Hearts | 2-0 | Mothrwell | | Graham, C |
| 25-Aug-24 SPFL 2024/2025 - M.3 | League | Mothrwell | 3-1 | Hearts | | Beaton, J |
| 02-Jan-25 SPFL 2024/2025 - M.21 | League | Hearts | 1-0 | Mothrwell | | Muir |
| 12-Apr-25 SPFL 2024/2025 - M.33 | League | Mothrwell | 0-0 | Hearts | | Clancy |
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