| # | | | | Player | | Height | |
Age | | | Position |
Team |
| 1 | |
 | |
Casillas
(c) | | 1.85 | | 27 | | | GK |  R.Madrid |
| 2 | |
 | |
Albiol
| | 1.90 | | 22 | | | DF Centre-back | Valencia |
| 2 | |
 | |
Busquets
| | 1.89 | | 20 | | | MF Defensive midfielder | Barcelona |
| 2 | |
 | |
Monreal, Nacho
| | 1.78 | | 22 | | | DF Left-back/Centre-back | Osasuna |
| 3 | |
 | |
Piqué
| | 1.92 | | 21 | | | DF Centre-back | Barcelona |
| 3 | |
 | |
Riera
| | 1.88 | | 26 | | | MF Left-midfield/Left-back | Espanyol |
| 4 | |
| |
Riera
| | 1.88 | | 26 | | | MF Left-midfield/Left-back | Espanyol |
| 4 | |
 | |
Marchena
| | 1.82 | | 29 | | | DF Centre-back/Defensive midfielder | Valencia |
| 4 | |
| |
Albiol
| | 1.90 | | 22 | | | DF Centre-back | Valencia |
| 4 | |
| |
Juanito
| | 1.82 | | 32 | | | DF Centre-back | Betis |
| 5 | |
 | |
Puyol
(c) | | 1.78 | | 30 | | | DF Centre-back/Right-back | Barcelona |
| 5 | |
| |
Busquets
| | 1.89 | | 20 | | | MF Defensive midfielder | Barcelona |
| 6 | |
 | |
Silva
| | 1.70 | | 22 | | | MF Attacking midfielder/Left-midfield | Valencia |
| 6 | |
 | |
Mata
| | 1.70 | | 20 | | | MF Attacking midfielder/Either side wing | Valencia |
| 6 | |
 | |
Iniesta
| | 1.70 | | 24 | | | MF Attacking midfielder/Left-wing | Barcelona |
| 6 | |
 | |
Santi Cazorla
| | 1.68 | | 23 | | | MF Attacking midfielder/Left-wing | Villarreal |
| 7 | |
 | |
Villa
| | 1.75 | | 26 | | | FW Striker/Left-wing | Valencia |
| 7 | |
 | |
Güiza
| | 1.82 | | 28 | | | FW Striker |  Fenerbhce |
| 7 | |
 | |
Negredo, A
| | 1.85 | | 23 | | | FW Striker | Almeria |
| 8 | |
 | |
Xavi
| | 1.70 | | 28 | | | MF Box-to-Box midfielder | Barcelona |
| 8 | |
| |
Silva
| | 1.70 | | 22 | | | MF Attacking midfielder/Left-midfield | Valencia |
| 9 | |
 | |
Torres
| | 1.86 | | 24 | | | FW Striker |  Liverpool |
| 9 | |
 | |
Diego Capel
| | 1.73 | | 20 | | | FW Left-wing/Right-wing | Sevilla |
| 10 | |
| |
Riera
| | 1.88 | | 26 | | | MF Left-midfield/Left-back | Espanyol |
| 10 | |
 | |
Fàbregas
| | 1.79 | | 21 | | | MF Attacking midfielder | Arsenal |
| 11 | |
| |
Santi Cazorla
| | 1.68 | | 23 | | | MF Attacking midfielder/Left-wing | Villarreal |
| 11 | |
 | |
Capdevila
| | 1.82 | | 30 | | | DF Left-back | Villarreal |
| 12 | |
 | |
Reina
| | 1.88 | | 25 | | | GK | Liverpool |
| 12 | |
| |
Casillas
(c) | | 1.85 | | 27 | | | GK | R.Madrid |
| 13 | |
 | |
Bojan K
| | 1.72 | | 17 | | | FW | Barcelona |
| 13 | |
| |
Busquets
| | 1.89 | | 20 | | | MF Defensive midfielder | Barcelona |
| 13 | |
| |
Mata
| | 1.70 | | 20 | | | MF Attacking midfielder/Either side wing | Valencia |
| 13 | |
| |
Iraola
| | 1.81 | | 26 | | | DF Right-back | Athletic |
| 13 | |
 | |
Llorente, Fernando (1985)
| | 1.94 | | 23 | | | FW Striker | Athletic |
| 14 | |
 | |
Xabi Alonso
| | 1.83 | | 26 | | | MF Defensive midfielder | Liverpool |
| 15 | |
 | |
Sergio Ramos
| | 1.83 | | 22 | | | DF Centre-back | R.Madrid |
| 15 | |
| |
Riera
| | 1.88 | | 26 | | | MF Left-midfield/Left-back | Espanyol |
| 16 | |
| |
Marcos Senna
| | 1.75 | | 32 | | | MF Defensive midfielder | Villarreal |
| 16 | |
 | |
Arbeloa
| | 1.84 | | 25 | | | DF Right-back/Left-back | Liverpool |
| 17 | |
| |
Güiza
| | 1.82 | | 28 | | | FW Striker | Fenerbhce |
| 17 | |
| |
Iraola
| | 1.81 | | 26 | | | DF Right-back | Athletic |
| 18 | |
| |
Riera
| | 1.88 | | 26 | | | MF Left-midfield/Left-back | Espanyol |
| 18 | |
| |
Silva
| | 1.70 | | 22 | | | MF Attacking midfielder/Left-midfield | Valencia |
| 18 | |
| |
Santi Cazorla
| | 1.68 | | 23 | | | MF Attacking midfielder/Left-wing | Villarreal |
| 19 | |
| |
Mata
| | 1.70 | | 20 | | | MF Attacking midfielder/Either side wing | Valencia |
| 20 | |
| |
Llorente, Fernando (1985)
| | 1.94 | | 23 | | | FW Striker | Athletic |
| 21 | |
| |
Marchena
| | 1.82 | | 29 | | | DF Centre-back/Defensive midfielder | Valencia |
| 22 | |
| |
Silva
| | 1.70 | | 22 | | | MF Attacking midfielder/Left-midfield | Valencia |
| 23 | |
| |
Busquets
| | 1.89 | | 20 | | | MF Defensive midfielder | Barcelona |
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